top of page

2019

E. Hampson, S. Amin, J. M. Cameron, J. Kyo, J. A. Watts, H. Oshio, and G. N. Newton (2019). “Asymmetric hybrid polyoxometalates: a new platform for multifunctional redox‐active nanomaterials” Angew. Chem. Int. Ed. In press (DOI:10.1002/anie.201912046).​

 

J. W. Jordan, G. A. Lowe, R. L. McSweeney, C. T. Stoppiello, R. W. Lodge, S. Skowron, J. Biskupek,  G. A. Rance, U. Kaiser, D. A. Walsh, G. N. Newton and A. N. Khlobystov, (2019). “Host–Guest Hybrid Redox Materials Self‐Assembled from Polyoxometalates and Single‐Walled Carbon Nanotubes.” Adv. Mater., 31, 1904182. 

 

T. Shiga, R. Saiki, L. Akiyama, R. Kumai, D. Natke, F. Renz, J. Cameron, G. N. Newton and H. Oshio (2019). "A Bronsted ligand molecular switch with five accessible states." Angew. Chem. Int. Ed. 58: 5658–5662.

 

S. Amin, J. M. Cameron, J. A. Watts, D. A. Walsh, V. Sans and G. N. Newton, (2019). “Effects of chain length on the size, stability, and electronic structure of redox-active organic–inorganic hybrid polyoxometalate micelles.” Mol. Syst. Des. Eng., 4, 995-999.

 

T. Shiga, D. Ishikawa, M. Tachibana, R. Saiki, G. N. Newton, H. Oshio, (2019). “Spin crossover behaviour of a tetranuclear iron(II) grid complex with a hydroxyl-group functionalized multidentatae ligand.” J. Mag. Mag. Mater. 485, 16-20.

 

R. Saiki, H. Miyamoto, H. Sagayama, R. Kumai, G. N. Newton, T. Shiga and H. Oshio (2019). "Substituent dependence on the spin crossover behaviour of mononuclear Fe(ii) complexes with asymmetric tridentate ligands." Dalton Trans. 48, 3231-3236. 

 

A. J. Kibler, C. Martin, J. M. Cameron, A. Rogalska, J. Dupont, D. A. Walsh and G. N. Newton (2019). "Physical and Electrochemical Modulation of Polyoxometalate Ionic Liquids via Organic Functionalization." Eur. J. Inorg. Chem. (3-4): 456-460 

 

2018

 

Wales, D. J.; Cao, Q.; Kastner, K.; Karjalainen, E.; Newton, G. N.; Sans, V., 3D-Printable Photochromic Molecular Materials for Reversible Information Storage. Advanced Materials 2018, 30 (26).

 

Shiga, T.; Sato, Y.; Tachibana, M.; Sato, H.; Matsumoto, T.; Sagayama, H.; Kumai, R.; Murakami, Y.; Newton, G. N.; Oshio, H., Carboxylic Acid Functionalized Spin-Crossover Iron(II) Grids for Tunable Switching and Hybrid Electrode Fabrication. Inorganic Chemistry 2018, 57 (22), 14013-14017.

Shiga, T.; Newton, G. N.; Oshio, H., Pre-programmed self-assembly of polynuclear clusters. Dalton Transactions 2018, 47 (22), 7384-7394.

Shiga, T.; Miyamoto, H.; Newton, G. N.; Oshio, H., Two-electron redox-active tricyano iron(II) complex with 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine as a building block for coordination polymers. Dalton Transactions 2018, 47 (38), 13402-13407.

Shiga, T.; Kumamaru, R.; Newton, G. N.; Oshio, H., Cobalt complexes with redox-active anthraquinone-type ligands. Dalton Transactions 2018, 47 (23), 7804-7811.

Kibler, A. J.; Newton, G. N., Tuning the electronic structure of organic-inorganic hybrid polyoxometalates: The crucial role of the covalent linkage. Polyhedron 2018, 154, 1-20.

Cameron, J. M.; Wales, D. J.; Newton, G. N., Shining a light on the photo-sensitisation of organic-inorganic hybrid polyoxometalates. Dalton Transactions 2018, 47 (15), 5120-5136.

Cameron, J. M.; Fujimoto, S.; Wei, R.-J.; Newton, G. N.; Oshio, H., Post-functionalization of a photoactive hybrid polyoxotungstate. Dalton Transactions 2018, 47 (31), 10590-10594.

2017

Saiki, R.; Yoshida, N.; Hoshino, N.; Newton, G. N.; Shiga, T.; Oshio, H., An Antiferromagnetically Coupled Heterometal Cu6Fe Wheel. Chemistry Letters 2017, 46 (8), 1197-1199.

Mitsumoto, K.; Cameron, J. M.; Wei, R.-J.; Nishikawa, H.; Shiga, T.; Nihei, M.; Newton, G. N.; Oshio, H., A Multi-Redox Responsive Cyanometalate-Based Metallogel. Chem.-Eur. J. 2017, 23 (7), 1502-1506.

Kuramochi, S.; Shiga, T.; Cameron, J.; Newton, G.; Oshio, H., Synthesis, Crystal Structures and Magnetic Properties of Composites Incorporating an Fe(II) Spin Crossover Complex and Polyoxometalates. Inorganics 2017, 5 (4).

Kastner, K.; Kibler, A. J.; Karjalainen, E.; Fernandes, J. A.; Sans, V.; Newton, G. N., Redox-active organic–inorganic hybrid polyoxometalate micelles. Journal of Materials Chemistry A 2017, 5 (23), 11577-11581.

Fujimoto, S.; Cameron, J. M.; Wei, R.-J.; Kastner, K.; Robinson, D.; Sans, V.; Newton, G. N.; Oshio, H., A Simple Approach to the Visible-Light Photoactivation of Molecular Metal Oxides. Inorganic Chemistry 2017, 56 (20), 12169-

12177.

Cameron, J. M.; Fujimoto, S.; Kastner, K.; Wei, R.-J.; Robinson, D.; Sans, V.; Newton, G. N.; Oshio, H. H., Orbital Engineering: Photoactivation of an Organofunctionalized Polyoxotungstate. Chem.-Eur. J. 2017, 23 (1), 47-50.

 

2016

Wei, R.-J.; Shiga, T.; Newton, G. N.; Robinson, D.; Takeda, S.; Oshio, H., A Cyanide-Bridged Magnetically Switchable Cage with Encapsulated Water Molecules. Inorganic Chemistry 2016, 55 (23), 12114-12117.

Wei, R.-J.; Nakahara, R.; Cameron, J. M.; Newton, G. N.; Shiga, T.; Sagayama, H.; Kumai, R.; Murakami, Y.; Oshio, H., Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex. Dalton Transactions 2016, 45 (43), 17104-17107.

 

Sakurai, T.; Saiki, R.; Wei, R. J.; Newton, G. N.; Takuya, S. A.; Oshio, H., Oxalate-bridged heterometallic chains with monocationic dabco derivatives. Dalton Transactions 2016, 45 (41), 16182-16189.

Newton, G. N.; Hoshino, N.; Matsumoto, T.; Shiga, T.; Nakano, M.; Nojiri, H.; Wernsdorfer, W.; Furukawa, Y.; Oshio, H., Studies on the Magnetic Ground State of a Spin Mobius Strip. Chem.-Eur. J. 2016, 22 (40), 14205-14212.

 

2015

Terashima, S.; Newton, G. N.; Shiga, T.; Oshio, H., Planar trinuclear complexes with linear arrays of metal ions. Inorganic Chemistry Frontiers 2015, 2 (2), 125-128.

Sato, H.; Yamaguchi, M.; Onuki, T.; Noguchi, M.; Newton, G. N.; Shiga, T.; Oshio, H., Pentanuclear and Octanuclear Manganese Helices. European Journal of Inorganic Chemistry 2015, 2015 (13), 2193-2198.

Kuramochi, S.; Newton, G. N.; Shiga, T.; Oshio, H., Structure and Magnetic Properties of a Sulfate-bridged Tetracosanuclear Manganese Cluster. Chemistry Letters 2015, 44 (6), 746-748.

Kastner, K.; Forster, J.; Ida, H.; Newton, G. N.; Oshio, H.; Streb, C., Controlled Reactivity Tuning of Metal-Functionalized Vanadium Oxide Clusters. Chem.-Eur. J. 2015, 21 (21), 7686-7689.

 

Ida, H.; Shiga, T.; Newton, G. N.; Oshio, H., Syntheses, structures and magnetism of mixed-valence Mn19 and Mn21 complexes supported by alkylamine-based alkoxo-bridging ligands. Inorganic Chemistry Frontiers 2015, 2 (6), 538-543.

 

2014

Shiga, T.; Tetsuka, T.; Sakai, K.; Sekine, Y.; Nihei, M.; Newton, G. N.; Oshio, H., Cyanide-Bridged Decanuclear Cobalt-Iron Cage. Inorganic Chemistry 2014, 53 (12), 5899-5901.

Shiga, T.; Tetsuka, T.; Iijima, F.; Newton, G. N.; Oshio, H., Self-assembly of a cobalt octacyanotungstate network into a giant chiral helix. Polyhedron 2014, 68, 157-163.

Shiga, T.; Takeo, M.; Iijima, F.; Newton, G. N.; Oshio, H., Syntheses, structures and magnetic properties of two-dimensional chiral coordination polymers based on a tetradentate chiral ligand. New J. Chem. 2014, 38 (5), 1946-1949.

Shiga, T.; Maruyama, K.; Newton, G. N.; Inglis, R.; Brechin, E. K.; Oshio, H., Chiral Single-Chain Magnet: Helically Stacked [(Mn2CuII)-Cu-III] Triangles. Inorganic Chemistry 2014, 53 (9), 4272-4274.

Newton, G. N.; Mitsumoto, K.; Wei, R.-J.; Iijima, F.; Shiga, T.; Nishikawa, H.; Oshio, H., Lability-Controlled Syntheses of Heterometallic Clusters. Angewandte Chemie-International Edition 2014, 53 (11), 2941-2944.

Matsumoto, T.; Newton, G. N.; Shiga, T.; Hayami, S.; Matsui, Y.; Okamoto, H.; Kumai, R.; Murakami, Y.; Oshio, H., Programmable spin-state switching in a mixed-valence spin-crossover iron grid. Nature Communications 2014, 5.

Kuramochi, S.; Newton, G. N.; Shiga, T.; Oshio, H., Electrochemical Carbon Dioxide Reduction Catalyzed by a Dinuclear Ruthenium Complex with a Flexible Bridging Ligand. Chemistry Letters 2014, 43 (8), 1222-1223.

 

2013

Shiga, T.; Oshiro, E.; Nakayama, N.; Mitsumoto, K.; Newton, G. N.; Nishikawa, H.; Oshio, H., Dimerized Spin-Crossover Iron(II) Complexes as Supramolecular Anion Capsules. European Journal of Inorganic Chemistry 2013, 2013 (5-6), 781-787.

 

Shiga, T.; Noguchi, M.; Sato, H.; Matsumoto, T.; Newton, G. N.; Oshio, H., Triple-stranded ferric helices: a pi-pi interaction-driven structural hierarchy of Fe-5, Fe-7, and Fe-17 clusters. Dalton Transactions 2013, 42 (45), 16185-16193.

Sato, H.; Miya, L.; Mitsumoto, K.; Matsumoto, T.; Shiga, T.; Newton, G. N.; Oshio, H., Multiredox Active [3 x 3] Copper Grids. Inorganic Chemistry 2013, 52 (17), 9714-9716.

Newton, G. N.; Sato, H.; Shiga, T.; Oshio, H., Stepwise replacement of nickel with cobalt ions in a [Ni-6] cluster. Dalton Transactions 2013, 42 (19), 6701-6704.

Cameron, J. M.; Newton, G. N.; Busche, C.; Long, D.-L.; Oshio, H.; Cronin, L., Synthesis and characterisation of a lanthanide-capped dodecavanadate cage. Chemical Communications 2013, 49 (33), 3395-3397.

Baker, M. L.; Kitagawa, Y.; Nakamura, T.; Tazoe, K.; Narumi, Y.; Kotani, Y.; Iijima, F.; Newton, G. N.; Okumura, M.; Oshio, H.; Nojiri, H., X-ray Magnetic Circular Dichroism Investigation of the Electron Transfer Phenomena Responsible for Magnetic Switching in a Cyanide-Bridged [CoFe] Chain. Inorganic Chemistry 2013, 52 (24), 13956-13962.

 

2012

Shiga, T.; Iijima, F.; Tetsuka, T.; Newton, G. N.; Oshio, H., [M6M′4] Cage Compounds with Chiral Bidentate Ligands. Macromolecular Symposia 2012, 317-318 (1), 286-292.

Newton, G. N.; Shiga, T.; Oshio, H., An antiferromagnetic {Mn8} ring supported by planar multidentate ligands. Science China Chemistry 2012, 55 (6), 973-977.

Mitsumoto, K.; Nishikawa, H.; Newton, G. N.; Oshio, H., Encapsulation controlled single molecule magnetism in tetrathiafulvalene-capped cyanide-bridged cubes. Dalton Transactions 2012, 41 (44), 13601-13608.

Krueger, C.; Sato, H.; Matsumoto, T.; Shiga, T.; Newton, G. N.; Renz, F.; Oshio, H., A rectangular Ni-Fe cluster with unusual cyanide bridges. Dalton Transactions 2012, 41 (37), 11270-11272.

Iijima, F.; Hasumi, K.; Shiga, T.; Newton, G. N.; Oshio, H., Linking Magnetic Clusters: Ferrimagnetic Interactions in a Nonanuclear Nickel(II) Cluster. Chemistry Letters 2012, 41 (7), 691-692.

Hoshino, N.; Iijima, F.; Newton, G. N.; Yoshida, N.; Shiga, T.; Nojiri, H.; Nakao, A.; Kumai, R.; Murakami, Y.; Oshio, H., Three-way switching in a cyanide-bridged [CoFe] chain. Nature Chemistry 2012, 4 (11), 921-926.

 

2011

Shiga, T.; Noguchi, M.; Matsumoto, T.; Sato, H.; Tahira, H.; Newton, G. N.; Oshio, H., A series of tetranuclear [2 × 2] grid complexes derived from an asymmetric ligand: Structural differences based on metal ion affinities. Pure and Applied Chemistry 2011, 83 (9), 1721-1729.

 

Newton, G. N.; Yamashita, S.; Hasumi, K.; Matsuno, J.; Yoshida, N.; Nihei, M.; Shiga, T.; Nakano, M.; Nojiri, H.; Wernsdorfer, W.; Oshio, H., Redox-Controlled Magnetic {Mn-13} Keggin Systems. Angewandte Chemie-International Edition 2011, 50 (25), 5715-5719.

Newton, G. N.; Onuki, T.; Shiga, T.; Noguchi, M.; Matsumoto, T.; Mathieson, J. S.; Nihei, M.; Nakano, M.; Cronin, L.; Oshio, H., Mapping the Sequential Self-Assembly of Heterometallic Clusters: From a Helix to a Grid. Angewandte Chemie-International Edition 2011, 50 (21), 4844-4848.

Newton, G. N.; Nihei, M.; Oshio, H., Cyanide-Bridged Molecular Squares - The Building Units of Prussian Blue. European Journal of Inorganic Chemistry 2011, 2011 (20), 3031-3042.

 

2010

Shiga, T.; Newton, G. N.; Mathieson, J. S.; Tetsuka, T.; Nihei, M.; Cronin, L.; Oshio, H., Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages. Dalton Transactions 2010, 39 (20), 4730-4733.

 

Seeber, G.; Cooper, G. J. T.; Newton, G. N.; Rosnes, M. H.; Long, D.-L.; Kariuki, B. M.; Kögerler, P.; Cronin, L., Following the self assembly of supramolecular MOFs using X-ray crystallography and cryospray mass spectrometry. Chemical Science 2010, 1 (1), 62-67.

Ochoa, M. N. C.; Cooper, G. J. T.; Newton, G. N.; Long, D. L.; Seeber, G.; Cronin, L., Supramolecular Architectures of Copper(II) Perchlorate Complexes of cis,trans-1,3,5-Triaminocyclohexane Assembled Exploiting the Delicate Balance Between Weak and Strong Interactions. Zeitschrift Fur Naturforschung Section B-a Journal of Chemical Sciences 2010,

65 (3), 304-310.

Matsumoto, T.; Shiga, T.; Noguchi, M.; Onuki, T.; Newton, G. N.; Hoshino, N.; Nakano, M.; Oshio, H., Contrasting Magnetism of [Mn-4(III)] and [(Mn2Mn2III)-Mn-II] Squares. Inorganic Chemistry 2010, 49 (2), 368-370.

Ivanov, N. B.; Schnack, J.; Schnalle, R.; Richter, J.; Koegerler, P.; Newton, G. N.; Cronin, L.; Oshima, Y.; Nojiri, H., Heat Capacity Reveals the Physics of a Frustrated Spin Tube. Physical Review Letters 2010, 105 (3).

 

2009

Shiga, T.; Onuki, T.; Matsumoto, T.; Nojiri, H.; Newton, G. N.; Hoshino, N.; Oshio, H., Undecanuclear mixed-valence 3d-4f bimetallic clusters. Chemical Communications 2009,  (24), 3568-3570.

 

Shiga, T.; Matsumoto, T.; Noguchi, M.; Onuki, T.; Hoshino, N.; Newton, G. N.; Nakano, M.; Oshio, H., Cobalt Antiferromagnetic Ring and Grid Single-Molecule Magnet. Chemistry-an Asian Journal 2009, 4 (11), 1660-1663.

Newton, G. N.; Cooper, G. J. T.; Schuch, D.; Shiga, T.; Khanra, S.; Long, D.-L.; Oshio, H.; Cronin, L., cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe-III and Pd-II coordination clusters. Dalton Transactions 2009,  (9), 1549-1553.

Mathieson, J. S.; Cooper, G. J. T.; Pickering, A. L.; Keller, M.; Long, D.-L.; Newton, G. N.; Cronin, L., Monitoring the Formation of Coordination Complexes Using Electrospray Mass Spectrometry. Chemistry-an Asian Journal 2009, 4 (5), 681-687.

Cooper, G. J. T.; Newton, G. N.; Long, D.-L.; Koegerler, P.; Rosnes, M. H.; Keller, M.; Cronin, L., Exploring a Series of Isostructural Dodecanuclear Mixed Ni:Co Clusters: Toward the Control of Elemental Composition Using pH and Stoichiometry. Inorganic Chemistry 2009, 48 (3), 1097-1104.

 

2008

Rancan, M.; Newton, G. N.; Muryn, C. A.; Pritchard, R. G.; Timco, G. A.; Cronin, L.; Winpenny, R. E. P., Chemistry and supramolecular chemistry of chromium horseshoes. Chemical Communications 2008,  (13), 1560-1562.

 

Pradeep, C. P.; Long, D.-L.; Newton, G. N.; Song, Y.-F.; Cronin, L., Supramolecular metal oxides: Programmed hierarchical assembly of a protein-sized 21 kDa [(C16H36N)(19){H2NC(CH2O)(3)P2V3W15O59}(4)](5-) polyoxometalate assembly. Angewandte Chemie-International Edition 2008, 47 (23), 4388-4391.

Newton, G. N.; Cooper, G. J. T.; Koegerler, P.; Long, D.-L.; Cronin, L., Trading templates: Supramolecular transformations between {Co-13(II)} and {Co-12(II)} nanoclusters. Journal of the American Chemical Society 2008, 130 (3), 790-+.

 

2007

Cooper, G. J. T.; Newton, G. N.; Kogerler, P.; Long, D.-L.; Engelhardt, L.; Luban, M.; Cronin, L., Structural and compositional control in {M-12} cobalt and nickel coordination clusters detected magnetochemically and with cryospray mass spectrometry. Angewandte Chemie-International Edition 2007, 46 (8), 1340-1344.

 

2006

Newton, G. N.; Cooper, G. J. T.; Long, D.-L.; Kögerler, P.; Cronin, L., Synthetic, structural and magnetic characterisation of a one-dimensional nickel chain constructed using cis,trans-1,3,5-triaminocyclohexane as a building block. Journal of Molecular Structure 2006, 796 (1-3), 23-27.

bottom of page